--------------------------------------------------------------------- Atmospheric SF6 Dry Air Mole Fractions from the NOAA GMD Carbon Cycle Cooperative Global Air Sampling Network, 1997-2006 Version: 2016-04-12 -------------------------------------------------------------------- CONTENTS 1. Data source and contacts 2. Use of data 2.1 Citation 3. Reciprocity 4. Warnings 5. Update notes 6. Introduction 7. DATA - General Comments 7.1 DATA - Sampling Locations 7.2 DATA - File Name Description 7.3 DATA - Event with single parameter 7.4 DATA - Event with multiple parameters 7.5 DATA - QC Flags 7.6 DATA - Monthly Averages 8. Data retrieval 9. References -------------------------------------------------------------------- 1. DATA SOURCE AND CONTACTS National Oceanic and Atmospheric Administration (NOAA) Earth System Research Laboratory (ESRL) Global Monitoring Division (GMD) Carbon Cycle Greenhouse Gases (CCGG) Correspondence concerning these data should be directed to: Dr. Edward J. Dlugokencky NOAA ESRL Global Monitoring Division 325 Broadway, GMD-1 Boulder, Colorado, 80305 USA Telephone: 303 497-6228 Electronic Mail: ed.dlugokencky@noaa.gov Patricia M. Lang NOAA ESRL GMD Kenneth A. Masarie NOAA ESRL GMD -------------------------------------------------------------------- 2. USE OF DATA These data are made freely available to the public and the scientific community in the belief that their wide dissemination will lead to greater understanding and new scientific insights. The availability of these data does not constitute publication of the data. NOAA relies on the ethics and integrity of the user to insure that ESRL receives fair credit for their work. If the data are obtained for potential use in a publication or presentation, ESRL should be informed at the outset of the nature of this work. If the ESRL data are essential to the work, or if an important result or conclusion depends on the ESRL data, co-authorship may be appropriate. This should be discussed at an early stage in the work. Manuscripts using the ESRL data should be sent to ESRL for review before they are submitted for publication so we can insure that the quality and limitations of the data are accurately represented. 2.1 CITATION Please reference these data as -------------------------------------------------------------------- 3. RECIPROCITY Use of these data implies an agreement to reciprocate. Laboratories making similar measurements agree to make their own data available to the general public and to the scientific community in an equally complete and easily accessible form. Modelers are encouraged to make available to the community, upon request, their own tools used in the interpretation of the ESRL data, namely well documented model code, transport fields, and additional information necessary for other scientists to repeat the work and to run modified versions. Model availability includes collaborative support for new users of the models. -------------------------------------------------------------------- 4. WARNINGS Every effort is made to produce the most accurate and precise measurements possible. However, we reserve the right to make corrections to the data based on recalibration of standard gases or for other reasons deemed scientifically justified. We are not responsible for results and conclusions based on use of these data without regard to this warning. -------------------------------------------------------------------- 5. UPDATE NOTES +++++++++++++++++++++++++++++++ Lab-wide notes: 2015-08-03 The 3-letter site identification code for Ushuaia, Argentina (TDF) was changed to USH to be consistent with the WMO GAWSIS. 2011-10-07 We have introduced the term "measurement group", which identifies the group within NOAA and INSTAAR that made the actual measurement. We can now have multiple groups measuring some of the same trace gas species in our discrete samples. Measurement groups within NOAA and INSTAAR are ccgg: NOAA Carbon Cycle Greenhouse Gases (CCGG) hats: NOAA Halocarbons and other Atmospheric Trace Species (HATS) arl: INSTAAR Atmospheric Research Laboratory (ARL) sil: INSTAAR Stable Isotope Laboratory (SIL) curl: INSTAAR Laboratory for Radiocarbon Preparation and Research (CURL) We have also changed the file naming convention (see section "DATA - FILE NAME DESCRIPTION"). +++++++++++++++++++++++++++++++ Project-specific notes: 2015-11-20 Updated the content and format of event files to include elevation in meters above sea level (masl) and sample collection intake height in meters above ground level (magl). Elevation plus collection intake height equals altitude, which has always been included in the NOAA distribution. In adding these 2 fields, the event number column has moved. The new format is described in Sections 7.3 and 7.4. Users may find minor changes (from earlier distributions) to reported monthly mean values for the beginning months of data records. These changes are due to minor corrections to our curve fitting methods as first described by Thoning et al. (JGR,1989). 2013-08-27 Coordinates of some of the sample locations have changed. These changes improve the specified location based on new information. Changes tend to be minor and do not necessarily reflect a change in the actual sampling location. 2011-10-01 The data file format has been modified to include the measurement group and, additionally, the sample collection and analysis times now include second information (e.g., 2011 03 15 23 06 12). See section 7.3 for details. 2010-10-01 The format of the NOAA ESRL data records has been changed to include an estimate of the uncertainty associated with each measurement. The determination of the estimate is trace gas specific and described in section 6 (INTRODUCTION). +++++++++++++++++++++++++++++++ Parameter-specific notes: -------------------------------------------------------------------- 6. INTRODUCTION All samples were analyzed for SF6 at NOAA ESRL in Boulder, Colorado by gas chromatography with election capture detection, and each sample aliquot was referenced to the NOAA X2006 SF6 standard scale The average precision has been approximately 0.3 ppt. Data files in the subdirectories "ccg/sf6/flask/event" and "ccg/sf6/flask/month" list SF6 dry air mole fractions in pmol/mol based on measurements from the NOAA GMD Carbon Cycle Cooperative Global Air Sampling Network. The subdirectory "event" contains all measurements from air samples collected at each site and the subdirectory "month" contains monthly means determined from the data files in "event". Network sampling sites are listed in section 7.1. ------------------------------------------------------------------- 7. DATA - GENERAL COMMENTS Ambient and standard air samples are injected into the gas chromatograph (GC) with a sampling valve. Sulfur hexaflouride (SF6) is separated from other sample constituents using packed columns and detected by electron capture detector (ECD). This process is highly automated for field and laboratory operations. Instrument response of the sample must be compared to a standard of known SF6 content. Measurements are reported in units of picomol/mol (10^-12 mol SF6 per mol of dry air (pmol/mol) or parts per trillion (ppt)) relative to the NOAA X2006 SF6 standard scale. Reproducibility of our measurements, based on repeated analysis of air from a high-pressure cylinder, is approximately 0.04 pmol/mol over the period of our measurements. The absolute accuracy of our scale is estimated at 0.2%. The Pacific Ocean Cruise (POC, travelling between the US west coast and New Zealand or Australia) data have been merged and grouped into 5 degree latitude bins. For the South China Sea cruises (SCS) the data are grouped in 3 degree latitude bins. Sampling frequencies are approximately weekly for the fixed sites and average one sample every 3 weeks per latitude zone for POC and about one sample every week per latitude for SCS. Historically, samples have been collected using two general methods: flushing and then pressurizing glass flasks with a pump, or opening a stopcock on an evacuated glass flask; since 28 April 2003, only the former method is used. During each sampling event, a pair of flasks is filled. ------------------------------------------------------------------- 7.1 DATA - SAMPLING LOCATIONS For a summary of sampling locations, please visit http://www.esrl.noaa.gov/gmd/dv/site/site_table.html. IMPORTANT NOTES: 1. Data for all species may not be available for all sites listed in the table. 2. The exact location of a sampling site recorded in our database may change or become better defined over time. The latitude, longitude, and altitude of a sample event is based on the best information available at the time of sample collection. Differences in sample position associated with a particular site may be due to the site moving or changes in technology that permit a more accurate location determination. To view near real-time data, manipulate and compare data, and create custom graphs, please visit http://www.esrl.noaa.gov/gmd/dv/iadv/. ------------------------------------------------------------------- 7.2 DATA - FILE NAME DESCRIPTION Encoded into each file name are the parameter (trace gas identifier); sampling site; sampling project; laboratory ID number; measurement group; and optional qualifiers that further define the file contents. All file names use the following naming scheme: 1 2 3 4 5 [parameter]_[site]_[project]_[lab ID number]_[measurement group]_[optional 6 7 qualifiers].[file type] 1. [parameter] Identifies the measured parameter or trace gas species. (ex) co2 Carbon dioxide ch4 Methane co2c13 d13C (co2) merge more than one parameter 2. [site] Identifies the sampling site code. (ex) brw pocn30 car amt 3. [project] Identifies sampling platform and strategy. (ex) surface-flask surface-pfp surface-insitu aircraft-pfp aircraft-insitu tower-insitu 4. [lab ID number] A numeric field that identifies the measurement laboratory (1,2,3, ...). NOAA ESRL is lab number 1 (see http://www.esrl.noaa.gov/gmd/ccgg/obspack/labinfo.html). 5. [measurement group] Identifies the group within NOAA or INSTAAR that makes the actual measurement. See Section 5 (UPDATE NOTES) for details. (ex) ccgg hats arl sil 6. [optional qualifiers] Optional qualifier(s) may indicate data subsetting or averaging. Multiple qualifiers are delimited by an underscore (_). A more detailed description of the file contents is included within each data file. (ex) event All measurement results for all collected samples (discrete (flask) data only). hour_#### Computed hourly averages for the specified 4-digit year (quasi-continuous data only) HourlyData Computed hourly averages for entire record (quasi-continuous data only) DailyData Computed daily averages for entire record (quasi-continuous data only) day MonthlyData Computed monthly averages for entire record (quasi-continuous data only) month 7. [file type] We provide some NOAA Global Monitoring Division measurements in two unique file formats (netCDF and ASCII text). (ex) txt ASCII text file nc netCDF4 file ------------------------------------------------------------------- 7.3 DATA - EVENT WITH SINGLE PARAMETER The event data files in ftp://aftp.cmdl.noaa.gov/data/trace_gases/sf6/flask/surface/ use the following naming scheme (see Section 7.2): [parameter]_[site]_[project]_[lab ID number]_[measurement group]_[optional qualifiers].txt (ex) CH4_pocn30_surface-flask_1_ccgg.txt contains CH4 ccgg measurement results for all surface flask samples collected on the Pacific Ocean Cruise sampling platform and grouped at 30N +/- 2.5 degrees. (ex) CO2_brw_surface-flask_1_ccgg.txt contains CO2 ccgg measurement results for all surface flask samples collected at Barrow, Alaska. The data files contain multiple lines of header information followed by one record for each atmospheric measurement of a single parameter or trace gas species. Fields are defined as follows: Field 1: [SITE CODE] The three-character sampling location code (see above). Field 2: [YEAR] The sample collection date and time in UTC. Field 3: [MONTH] Field 4: [DAY] Field 5: [HOUR] Field 6: [MINUTE] Field 7: [SECOND] Field 8: [FLASK ID] The sample container ID. Field 9: [METHOD] A single-character code that identifies the sample collection method. The codes are: P - Sample collected using a portable, battery powered pumping unit. Two flasks are connected in series, flushed with air, and then pressurized to 1.2 - 1.5 times ambient pressure. D - Similar to P but the air passes through a condenser cooled to about 5 deg C to partially dry the sample. G - Similar to D but with a gold-plated condenser. T - Evacuated flask filled by opening an O-ring sealed stopcock. S - Flasks filled at NOAA ESRL observatories by sampling air from the in situ CO2 measurement air intake system. N - Before 1981, flasks filled using a hand-held aspirator bulb. After 1981, flasks filled using a pump different from those used in method P, D, or G. F - Five liter evacuated flasks filled by opening a ground glass, greased stopcock. Field 10: [TRACE GAS NAME] Gas identifier (e.g., co2, co2c13). Field 11: [MEASUREMENT GROUP] Identifies the group within NOAA and INSTAAR making the actual measurement (e.g., ccgg, hats, arl). See Section 5 (UPDATE NOTES) for details. Field 12: [MEASURED VALUE] Dry air mole fraction or isotopic composition. Missing values are denoted by -999.99[9]. Field 13: [ESTIMATED UNCERTAINTY] Estimated uncertainty of the reported measurement value. Missing values are denoted by -999.99[9]. Field 14: [QC FLAG] A three-character field indicating the results of our data rejection and selection process, described in section 7.5. Field 15: [INSTRUMENT] A 2-character code that identifies the instrument used for the measurement. Field 16: [YEAR] The measurement date and time in LT. Field 17: [MONTH] Field 18: [DAY] Field 19: [HOUR] Field 20: [MINUTE] Field 21: [SECOND] Field 22: [LATITUDE] The latitude where the sample was collected, (negative (-) numbers indicate samples collected in the Southern Hemipshere). Field 23: [LONGITUDE] The longitude where the sample was collected, (negative (-) numbers indicate samples collected in the Western Hemisphere). Field 24: [ALTITUDE] The altitude of the sample inlet (masl). The reported altitude is the surface elevation plus sample intake height. Field 25: [ELEVATION] Surface elevation (masl). Field 26: [INTAKE HEIGHT] Air sample collection height above ground level (magl). Field 27: [EVENT NUMBER] A long integer that uniquely identifies the sampling event. Fields in each line are delimited by whitespace. (ex) BRW 1971 10 19 01 20 00 48-71 N co2 CCGG 319.520 -999.990 N.. L1 1971 12 15 08 46 00 71.3200 -156.6000 13.00 11.00 2.00 26142 ------------------------------------------------------------------- 7.4 DATA - EVENT WITH MULTIPLE PARAMETERS On special request we can distribute a "merged" file, which includes for each sampling event, measurement results for muliple parameters or trace gas species. A merged file does not include all information found in a single parameter data file. For example, merged files exclude measurement uncertainty, analysis instrument ID and date and time for each parameter. Thus, the single parameter data file is our most comprehensive data archive. The format of a merged file is slightly different from single parameter event file. A "merged" file will have the word "merge" in the parameter field of the file name. The file name does not inform on the number of parameters included in the file. Merged data files use the following naming scheme (see Section 7.2): merge_[site]_[project]_[lab ID number]_[measurement group]_[optional qualifiers].txt (ex) merge_pocn30_surface-flask_1_ccgg.txt contains ccgg measurement results for two or more parameters for all surface flask samples collected on the Pacific Ocean Cruise sampling platform and grouped at 30N +/- 2.5 degrees. (ex) merge_brw_surface-flask_1_ccgg.txt contains ccgg measurement results for two or more parameters for all surface flask samples collected at Barrow, Alaska. The data files contain multiple lines of header information followed by one record for each atmospheric measurement of a single parameter or trace gas species. Fields are defined as follows: Field 1: [SITE CODE] The three-character sampling location code (see above). Field 2: [YEAR] The sample collection date and time in UTC. Field 3: [MONTH] Field 4: [DAY] Field 5: [HOUR] Field 6: [MINUTE] Field 7: [SECOND] Field 8: [FLASK ID] The sample container ID. Field 9: [METHOD] A single-character code that identifies the sample collection method. The codes are: P - Sample collected using a portable, battery powered pumping unit. Two flasks are connected in series, flushed with air, and then pressurized to 1.2 - 1.5 times ambient pressure. D - Similar to P but the air passes through a condenser cooled to about 5 deg C to partially dry the sample. G - Similar to D but with a gold-plated condenser. T - Evacuated flask filled by opening an O-ring sealed stopcock. S - Flasks filled at NOAA ESRL observatories by sampling air from the in situ CO2 measurement air intake system. N - Before 1981, flasks filled using a hand-held aspirator bulb. After 1981, flasks filled using a pump different from those used in method P, D, or G. F - Five liter evacuated flasks filled by opening a ground glass, greased stopcock. Field 10: [LATITUDE] The latitude where the sample was collected, (negative (-) numbers indicate samples collected in the Southern Hemipshere). Field 11: [LONGITUDE] The longitude where the sample was collected, (negative (-) numbers indicate samples collected in the Western Hemisphere). Field 12: [ALTITUDE] The altitude of the sample inlet (masl). The reported altitude is the surface elevation plus sample intake height. Field 13: [ELEVATION] Surface elevation (masl). Field 14: [INTAKE HEIGHT] Air sample collection height above ground level (magl). Field 15: [EVENT NUMBER] A long integer that uniquely identifies the sampling event. There is a group of 4 fields for each parameter and measurement group included in the merge file. Field ##+1: [TRACE GAS NAME] Gas identifier (e.g., co2, co2c13). Field ##+2: [MEASUREMENT GROUP] Identifies the group within NOAA and INSTAAR making the actual measurement (e.g., ccgg, hats, arl). See Section 5 (UPDATE NOTES) for details. Field ##+3: [MEASURED VALUE] Dry air mole fraction or isotopic composition. Missing values are denoted by -999.99[9]. Field ##+4: [QC FLAG] A three-character field indicating the results of our data rejection and selection process, described in section 7.5. Fields in each line are delimited by whitespace. (ex) BRW 2015 11 02 20 05 00 4827-99 P 71.3230 -156.6114 16.00 11.00 5.00 397570 co2 CCGG 400.480 ... co CCGG 105.340 ... ------------------------------------------------------------------- 7.5 QC FLAGS NOAA ESRL uses a 3-column quality control flag where each column is defined as follows: column 1 REJECTION flag. An alphanumeric other than a period (.) in the FIRST column indicates a sample with obvious problems during collection or analysis. This measurement should not be interpreted. column 2 SELECTION flag. An alphanumeric other than a period (.) in the SECOND column indicates a sample that is likely valid but does not meet selection criteria determined by the goals of a particular investigation. column 3 INFORMATION flag. An alphanumeric other than a period (.) in the THIRD column provides additional information about the collection or analysis of the sample. WARNING: A "P" in the 3rd column of the QC flag indicates the measurement result is preliminary and has not yet been carefully examined by the PI. The "P" flag is removed once the quality of the measurement has been determined. ------------------------------------------------------------------- 7.6 DATA - MONTHLY AVERAGES The monthly data files in ftp://aftp.cmdl.noaa.gov/data/trace_gases/sf6/flask/surface/ use the following naming scheme (see Section 7.2): [parameter]_[site]_[project]_[lab ID number]_[measurement group]_month.txt (ex) CH4_pocn30_surface-flask_1_ccgg_month.txt contains CH4 ccgg monthly mean values for all surface flask samples collected on the Pacific Ocean Cruise sampling platform and grouped at 30N +/- 2.5 degrees. (ex) CO2_brw_surface-flask_1_ccgg_month.txt contains CO2 ccgg monthly mean values for all surface flask samples collected at Barrow, Alaska. Monthly means are produced for each site by first averaging all valid measurement results in the event file with a unique sample date and time. Values are then extracted at weekly intervals from a smooth curve (Thoning et al., 1989) fitted to the averaged data and these weekly values are averaged for each month to give the monthly means recorded in the files. Flagged data are excluded from the curve fitting process. Some sites are excluded from the monthly mean directory because sparse data or a short record does not allow a reasonable curve fit. Also, if there are 3 or more consecutive months without data, monthly means are not calculated for these months. The data files contain multiple lines of header information followed by one line for each available month. Fields are defined as follows: Field 1: [SITE CODE] The three-character sampling location code (see above). Field 2: [YEAR] The sample collection year and month. Field 3: [MONTH] Field 4: [MEAN VALUE] Computed monthly mean value In these files a monthly mean value of -999.99 denotes months where there are insufficient data to calculate a monthly mean. ------------------------------------------------------------------- 8. DATA RETRIEVAL To transfer all files in a directory, it is more efficient to download the tar or zipped files. To transfer a tar file, use the following steps from the ftp prompt: 1. ftp> binary ! set transfer mode to binary 2. ftp> get filename.tar.gz ! transfer the file 3. ftp> bye ! leave ftp 4. $ gunzip filename.tar.gz ! unzip your local copy 5. $ tar xvf filename.tar ! unpack the file To transfer a zipped file, use the following steps from the ftp prompt: 1. ftp> binary ! set transfer mode to binary 2. ftp> get filename.zip ! transfer the file 3. ftp> bye ! leave ftp 4. $ unzip filename.zip ! uncompress your local copy ------------------------------------------------------------------- 9. REFERENCES -------------------------------------------------------------------