Comparison of secondary organic aerosol formed with an aerosol flow reactor and environmental reaction chambers : e ff ect of oxidant concentration , exposure time and seed particles on chemical composition and yield

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racy as measured with an aerosol mass spectrometer.This similarity in turn suggests that both in the flow reactor and in chambers, SOA chemical composition at low OH exposure is governed primarily by gas-phase OH oxidation of the precursors, rather than heterogeneous oxidation of the condensed particles.In general, SOA yields measured in the flow reactor are lower than measured in chambers for the range of equivalent OH exposures that can be measured in both the flow reactor and chambers.The influence of sulfate seed particles on isoprene SOA yield measurements was examined in the flow reactor.The studies show that seed particles increase the yield of SOA produced in flow reactors by a factor of 3 to 5 and may also account in part for higher SOA yields obtained in the chambers, where seed particles are routinely used.

Introduction
Laboratory and field studies over the last decade have shown that organic components of atmospheric particles constitute 20 to 50 % of the fine particle mass (PM) in the continental mid-latitudes, though the organic content can be higher (up to 90 %) in tropical forested regions (Kanakidou et al., 2005).On a global scale, 50-90 % of submicron organic PM is composed of oxygenated organic aerosol (Zhang et al., 2005) that is typically associated with secondary organic aerosol (SOA) formed by condensation of oxidized gas-phase species (Jimenez et al., 2009).Field studies indicate that SOA particles may influence cloud formation (Levin et al., 2014;Mei et al., 2013;Moore et al., 2012;Sihto et al., 2011) and may be optically active in the UV/Visible region of the electromagnetic spectrum (Zhang et al., 2011).These studies have also revealed the complexity of organic aerosol compositions and their chemical evolution via oxidative aging.The atmospheric lifetime of ambient SOA ranges from hours to weeks, providing a wide range of atmospheric exposures to a variety of oxidant species.Measured ambient SOA chemical compositions range from hydrocarbon-like organic aerosol, such as observed directly downwind of the Deepwater Horizon oil site during the 2010 Gulf Oil Spill (Bahreini et al., 2012;De Gouw et al., 2011), to highly oxygenated OA, such as background SOA observed worldwide (Zhang et al., 2007).Much of this complexity is due to the thousands of organic compounds found in atmospheric particulate matter, specifically low volatility, highly functionalized species (Hallquist et al., 2009).
Laboratory experiments conducted in environmental chambers have been essential in providing SOA physical and chemical properties as well as yield data for predicting the rate of atmospheric SOA formation due to oxidation of biogenic and anthropogenic volatile organic compounds (VOCs) (Spracklen et al., 2011).Substantial progress has been made in understanding reaction mechanisms and the factors that influence SOA yields and composition.For example, SOA yields appear to have a complex dependence on VOC : NO x ratio (Loza et al., 2014;Ng et al., 2007), precursor concentration/volatility (Presto and Donahue, 2006), and oxidant exposure (Lambe et al., 2012).Introduction

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Full Modeling observed atmospheric SOA levels therefore remains a challenge (Shrivastava et al., 2011;Bergström et al., 2012;Jo et al., 2013;Li et al., 2013) because of the large number of modeling parameters and associated sensitivities that are required to capture mechanistic details of SOA formation (Chen et al., 2013;Fountoukis et al., 2014).
Oxidant exposure is the integral of the oxidant species concentration and the sample residence time.Relatively low oxidant exposures are a major limitation of current environmental chamber techniques, which operate at OH concentrations ranging from approximately 10 6 to 10 7 molec cm −3 that are equal to or slightly more than daytime atmospheric OH concentrations.Chamber experiments are generally limited to residence times of several hours due to chamber deflation and the loss of oxidized vapors (Zhang et al., 2014) and/or particles to the chamber walls.This combination of low OH concentrations and residence time limits environmental chambers to simulating atmospheric aerosol particle lifetimes only up to 1 or 2 days, including the characterization of SOA yields.This limitation prevents the formation and the study of highly oxygenated SOA that is characteristic of aged atmospheric organic aerosol PM (Ng et al., 2010).Recently, aerosol flow reactors have been developed to study SOA formation and evolution equivalent to multiple days of atmospheric OH exposure.In these reactors OH concentrations are typically ∼ 10 9 molec cm −3 or greater, with reactor residence times of seconds to minutes (Kang et al., 2007;Hall IV et al., 2013;Keller and Burtscher, 2012;Lambe et al., 2011a;Slowik et al., 2012).With this range of OH concentrations and exposure times, flow reactors can simulate the full range of ambient levels of oxidation, measuring changes in SOA composition and yields over a wide range of equivalent atmospheric oxidation.Further, because of the short flow reactor residence times, experimental runs can be conducted on the scale of minutes rather than hours.
While flow reactors appropriately simulate the full range of integrated atmospheric oxidant exposures, in view of their short residence times and high oxidant concentrations it must be established how well the atmospheric aerosol chemistry is simulated (Renbaum and Smith, 2011).A growing set of studies indicates that flow reactor-Introduction

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Full generated SOA particles have compositions similar to ambient SOA, suggesting that the dominant oxidation reaction pathways in flow reactors are similar to those in ambient conditions (Bahreini et al., 2012;Lambe et al., 2012Lambe et al., , 2011b;;Kang et al., 2011;Massoli et al., 2010;Ortega et al., 2013;Slowik et al., 2012;Wang et al., 2012;Wong et al., 2011).However, these comparisons need to be extended over a wider range of reactants and experimental conditions than are currently available.
Here we describe systematic intercomparison studies of SOA chemistry and yields generated from a common set of precursors in a Potential Aerosol Mass (PAM) flow reactor (Lambe et al., 2011a) and four environmental chambers.SOA precursors studied are gas-phase alkane, biogenic, and aromatic compounds.SOA chemical composition and yield were characterized as a function of OH exposure.Additionally, the effect of sulfate seed particles on isoprene SOA yields was studied.Due to the limited oxidative exposure provided by the environmental chambers, direct comparison between the two techniques is possible only over a narrow range.However, reasonable extrapolations extend the range of interest.

Experimental
This manuscript compares properties of SOA produced in the PAM reactor to SOA produced in environmental chambers operated at the four institutions: California Institute of Technology (Caltech), Massachusetts Institute of Technology (MIT), Paul Scherrer Institut (PSI), and Carnegie Mellon University (CMU).The PAM reactor is a horizontal the methods used for OH radical generation, particle generation, and data analysis is provided below.

OH radical generation
In the flow reactor, OH radicals were produced in the absence of NO

Particle generation
Figure 1 shows the gas-phase SOA precursors used in these studies: two biogenic gases (isoprene, α-pinene), three aromatic compounds (toluene, m-xylene, naphthalene), and three alkanes (n-C 10 , cyclodecane, tricyclo[5.2.1.0 2,6]decane, also known as JP10).In the flow reactor, SOA was generated via gas-phase OH oxidation of precursors followed by homogeneous nucleation, or by condensation onto sulfuric acid or ammonium sulfate seed particles.The sulfuric acid seed particles were generated by OH oxidation of SO 2 together with the SOA precursor, and ammonium sulfate seed particles were generated by atomizing an ammonium sulfate solution.The particles were dried and introduced continuously into the flow reactor along with the gas-phase SOA precursor.In environmental chambers, SOA was generated via gas-phase OH oxidation of precursors usually followed by condensation onto ammonium sulfate seed particles.For long residence time chamber experiments, wall condensation of precursor gas-phase species can be significant.Seed particles are used in chamber studies to reduce wall effects.In some of the flow reactor experiments seed particles were also used to study their effect on SOA yields.

Particle monitoring and analysis
Particle number concentrations and size distributions were measured with a TSI scanning mobility particle sizer (SMPS).Aerosol mass spectra were measured with an Aerodyne time-of-flight aerosol mass spectrometers (ToF-AMS) (DeCarlo et al., 2006;Drewnick et al., 2005).Elemental analysis (Aiken et al., 2008) was performed on the AMS data to determine the bulk aerosol hydrogen-to-carbon (H/C) and oxygen-tocarbon (O/C) ratios along with the average aerosol carbon oxidation state (OSc) (Kroll et al., 2011).While AMS measurements provide basic information about SOA composition, additional supporting measurements are required to investigate SOA chemistry at the molecular level.Introduction

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Full SOA yields were calculated from the ratio of aerosol mass formed to precursor gas reacted.The aerosol mass was calculated from the integrated particle volume and the effective particle density (ρ = D va /D m ), where D va is the mean vacuum aerodynamic diameter obtained from the ToF-AMS and D m is the electric mobility diameter obtained from the SMPS.Flow reactor SOA yields were corrected using size-dependent bis (2ethylhexyl) sebacate wall-loss measurements (Lambe et al., 2011a); the average magnitude of these corrections was 32 % (±15 %) and represents an upper limit as it combines losses into and through the reactor.Caltech chamber yields were corrected for particle wall losses using size-dependent first-order loss coefficients determined from ammonium sulfate wall-loss measurements (Keywood et al., 2004).The magnitude of these particle wall loss corrections typically ranged from 10-30 %.
MIT chamber experiments were corrected for particle wall losses using the AMS organic-to-sulfate ratio to generate an upper limit and SMPS measurements of particle loss to generate a lower limit for aerosol yield (Hildebrandt et al., 2009).In the MIT chamber, these corrections were between a factor of 1.5 to 3.0 at the highest yields and OH exposures.Although the residence time in the flow reactor is much shorter than in the chambers, the surface-to-volume ratio in the PAM reactor is much greater.As a result particle losses are comparable in the two systems.Flow reactor SOA yields were also corrected for UV lamp-induced temperature increases by applying yield corrections of −0.02 per degree K of temperature rise (Qi et al., 2010;Stanier et al., 2007) relative to room temperature (∼ 293 K).These temperature corrections ranged from 0-28 % (mean correction ±1σ = 7±7 %).In the flow reactor, a known amount of precursor gas was introduced and the mass of reacted precursor gas was estimated from the OH exposure and known bimolecular rate constants (Atkinson, 1986).In environmental chamber studies, the mass of the remaining precursor gas was measured directly as a function of exposure time.Introduction

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Full Figure 2 shows representative ToF-AMS spectra of SOA generated in the PAM reactor and the Caltech chamber (Chhabra et al., 2010(Chhabra et al., , 2011) ) from the OH oxidation of α-pinene and naphthalene, used here as representative biogenic and anthropogenic precursors respectively.The flow reactor spectra are obtained at an OH exposure of 1.6 × 10 11 molec cm −3 s, or ∼ 1 day of equivalent atmospheric oxidation.The chamber spectra represent the SOA composition at peak aerosol formation (∼ 9 × 10 10 molec cm −3 s OH exposure).In this range the OH exposure for the PAM reactor and chamber are approximately the same, allowing for direct comparison.
The PAM flow reactor and the chamber produce particles with similar mass spectra, suggesting similar compositions.Features unique to α-pinene and naphthalene SOA are observed in both flow reactor-and chamber-obtained spectra, with linear correlation coefficients of r  anisms for organic aerosols (Heald et al., 2010).Typically, with oxidative aging the O/C ratio increases and H/C ratio of SOA decreases as oxygen-containing functional groups are added to a carbon backbone.Here, we use Van Krevelen diagrams to compare the composition of SOA formed in the flow reactor and environmental chambers for the organic precursors studied.Direct comparisons are possible in the overlapping OH exposure region.Typically the lowest OH exposures attained in the flow reactor overlap (or nearly overlap) with the highest OH exposures reached in environmental chambers (Table 1).
Figure 3 shows Van Krevelen diagrams obtained from laboratory SOA produced from the oxidation of gas-phase biogenic, aromatic, and alkane precursors.To simplify presentation, the data are displayed in three panels.Figure 3a shows biogenic SOA generated from isoprene and α-pinene, Fig. 3b shows SOA generated from aromatic compounds, and Fig. 3c shows SOA produced from alkanes.In most cases, for a specific SOA type the most-oxidized chamber SOA and the least-oxidized flow reactor SOA have similar Van Krevelen plots at integrated OH exposures between approximately 1 × 10 11 and 2 × 10 11 molec cm −3 s, or about 1-2 days of equivalent atmospheric oxidation.This observation suggests that in the range of available OH exposure overlap for the flow reactor and chambers, SOA elemental composition is similar whether the precursor is exposed to low OH concentrations over long exposure times or high OH concentrations over short exposures times.The flow reactor studies were done without added NO x , whereas some of the environmental chamber studies were conducted in the presence of NO x .The similarity in compositional parameters shown in Fig. 3 (e.g.H/C, O/C) were independent of the NO x levels used in the environmental chambers in the region studied, as has been observed in previous studies (Chhabra et al., 2011).The nitrogen-to-carbon (N/C) ratio ranged from 0.031 to 0.054 for SOA produced in the MIT chamber with added NO x (Hunter et al., 2014) but was not characterized for other measurements shown in Fig. 3. Introduction

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Full Recently, the average carbon oxidation state (OSc), defined as OSc = 2 × O/C − H/C, was proposed as a more accurate indicator of atmospheric oxidative aging processes than the O/C ratio alone because this measure takes into account the level of saturation of the carbon atoms in the SOA (Canagaratna et al., 2014;Kroll et al., 2011).
As will be demonstrated, OSc of lightly oxidized SOA is strongly precursor-dependent.
Figure 4 shows a scatter plot of OSc for flow reactor and chamber SOA for the eight gas-phase precursors studied.Different colored symbols are used to represent each of the environmental chambers used in the intercomparison.For each data point obtained from environmental chamber measurements, we used data from the flow reactor obtained at the OH exposure that was closest in magnitude.A total linear least squares fit to the data presented in Fig. 4 (PAM OSc = 1.1 • Chamber OSc − 0.16; r 2 = 0.54) indicates that there is no systematic OSc difference observed across multiple SOA types produced in chambers and in flow reactors.Figure 4 shows that the chambers and flow reactor provide similar OSc for a specific SOA type over the range of measured SOA composition for comparable OH exposures.The observed deviations between PAM and chamber OSc are no larger than deviations between two chambers (e.g.α-pinene SOA produced in Caltech and PSI chambers, and cyclodecane SOA produced in MIT and CMU chambers).

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Full of SOA precursor concentrations, NO x levels, and seed particle concentrations used in SOA yield studies is summarized in Table 2. Isolation of individual factors is beyond the scope of this intercomparison.Because mass spectra and elemental ratios of SOA are similar whether it is generated in an environmental chamber or in a flow reactor, we suggest that the differences in precursor concentration and UV wavelength (e.g.λ = 350 nm vs. λ = 254 nm) used in these studies have at most a minor effect on bulk composition.
Next we evaluate the influence of oxidant concentration and residence time on yields of SOA formed from common precursors in the PAM reactor and the Caltech and MIT environmental chambers.Figure 5 shows yields of SOA as a function of OH exposure for isoprene SOA (no added NO x ), α-pinene SOA (no added NO x ), and tricyclo [5.2.1.0 2,6]decane (JP-10) SOA, respectively.These precursors provide the broadest range of available yield values for intercomparison.Oxidation of isoprene forms SOA with low yield (Chhabra et al., 2010;Kroll et al., 2006), whereas α-pinene forms SOA with moderate yields (Eddingsaas et al., 2012) and JP-10 forms SOA with mass yields greater than unity (Hunter et al., 2014;Lambe et al., 2012).Yields of alkane SOA do not display a systematic NO x dependence (Loza et al., 2014); thus, to first order we assume different NO x levels between the MIT chamber and PAM reactor do not influence our comparison of measured JP-10 SOA yields.The following features are evident in Fig. 5: 1. SOA yields at comparable OH exposures are a factor of 2 to 10 lower in the flow reactor than in chambers, whereas the mass spectra, O/C and H/C of SOA generated in the chambers and flow reactor are similar (Figs.2-4).
2. SOA yields in the flow reactor and chambers track each other; that is, the maximum yield of isoprene SOA is approximately 0.03 in the flow reactor and 0.06 in the Caltech chamber (Fig. 5a).Likewise, the maximum yield of JP-10 SOA is 1.4 in the flow reactor and 1.6 in the MIT chamber (Fig. 5c).Introduction

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Full 3. In the flow reactor, in all cases the SOA yield first increases as a function of OH exposure and then decreases.In some cases there is also evidence of a slight decrease in SOA yields at higher OH exposure in chambers (e.g.Fig. 5c).
One reason for the lower SOA yield in flow reactors may be the relative timescales for oxidation in the gas-phase vs. condensation onto pre-existing aerosols.For example, over a representative range of particle surface area concentrations used in the flow reactor (10 to 100 µm 2 cm −3 ), condensation timescales range from approximately 2000 to 20 000 s assuming a mass accommodation coefficient of 0.1 (Saleh et al., 2013) and an average SOA molecular weight of 150 g mol −1 .While our measurements do not constrain the mass accommodation coefficient, these timescales suggest that the residence time in the flow reactor (100 s) may not be adequate to allow complete condensation of semivolatile organic gas-phase species into SOA.Another factor in causing the SOA yield difference may be due to the condensation conditions.All the chamber experiments displayed in this work were done in the presence of ammonium sulfate seed particles, whereas seed particles were not normally used in our flow reactor studies.The effect of seed particles on SOA yields in the flow reactor is examined further in Sect.3.5.
The observation that the yields track each other is a further indication that the reactive chemistry in the two systems is similar.The decrease in SOA yield subsequent to increase as a function of OH exposure is possibly due to gas-phase species carboncarbon bond breaking from continued oxidation or heterogeneous OH oxidation reactions at high OH exposure (Hunter et al., 2014;Lambe et al., 2012;Loza et al., 2012); this trend is most clearly evident in the flow reactor studies.These observations suggest that the first step in SOA formation is oxidation of gas-phase species leading to subsequent condensation.At low OH exposures equivalent to 1-2 days, heterogeneous reactions do not appear to play a significant role in SOA chemistry (Cappa and Wilson, 2012;Chen et al., 2013).Introduction

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Effect of seed particles on SOA yields
The chamber experiments discussed in Sects.3.1-3.4were performed in the presence of ammonium sulfate seeds to promote more rapid condensation of gas-phase species into SOA.We investigated in more detail the influence of sulfate seed particle loading and composition on SOA yields produced in the flow reactor.We hypothesize that a "seed effect" should be most pronounced for SOA types with low yields, and investigate this proposal for isoprene SOA whereas the effect of sulfate seeds on α-pinene SOA yields is minor (Kang et al., 2007).Figure 6 shows isoprene SOA yields in the flow reactor as a function of OH exposure using an ammonium sulfate seed particle mass concentration of 20 µg m −3 which is comparable to sulfate volume concentrations used by Chhabra et al. (2010).At an OH exposure of 2.9 × 10 11 molec cm −3 s or less in the flow reactor, the isoprene SOA yield with seeds added to the flow reactor compared to the SOA yield in the Caltech chamber is negligible.As the OH exposure is increased in the flow reactor, the SOA yield rises to a maximum value of 0.10 at 7.8 × 10 11 molec cm −3 s OH exposure and then decreases.We note that the same trend was observed without adding seed particles, although with lower SOA yields.The O/C ratio of the flow reactor SOA decreases from 0.63 to 0.59 when seeds are added at 7.8 × 10 11 molec cm −3 s OH exposure.Figure 6 supports the hypothesis that addition of seed particles promotes condensation, leading to higher SOA yields.Higher concentrations of seed particles may be required for condensation of gas-phase oxidation products to compete with continued OH oxidation in the gas phase.
To further investigate the effect of seeds on condensation, we measured isoprene SOA yields as a function of ammonium sulfate and sulfuric acid seed particle concentrations (Fig. 7).An OH exposure of 7.8×10 11 molec cm of ammonium sulfate seeds and 0.25 in the presence of sulfuric acid seeds.Increasing the seed particle concentration led to a continued increase in the yield, along with a decrease in the O/C ratio of the SOA as condensation of less-oxidized products was enhanced.The influence of seed acidity on isoprene SOA yields is well documented (Czoschke, 2003;Surratt et al., 2007;Offenberg et al., 2009), and the magnitude of the SOA yield enhancement in the presence of acidic seeds relative to neutral seeds in our work (factor of 2-3) is similar to these previous studies.Because a systematic isoprene SOA yield enhancement in the presence of neutral seeds (relative to unseeded conditions) is not observed in chamber studies (Chhabra et al., 2010;Brégonzio-Rozier et al., 2014), these measurements suggest seed particles are required in flow reactor measurements in order to more closely simulate condensation conditions in environmental chambers.

Conclusions
We performed a systematic intercomparison study of the chemistry and yields of SOA generated from OH oxidation of a common set of gas-phase precursors in several environmental chambers and a flow reactor.The most significant experimental parameters that varied between chambers and the flow reactor were OH concentration, residence time, and use of seed particles to promote condensation of oxidized vapors.The OH concentrations were 100 to 1000 times higher in the flow reactor, and residence times were 100 to 400 times higher in the environmental chambers.Within the range of approximate OH exposure overlap of (1-4) ×10 11 molec cm −3 s, the SOA mass spectra and oxidation state were similar in both systems.The SOA yields for representative systems tracked each other but were lower in the flow reactor, probably in part because chamber SOA experiments were done with seed particles to promote condensation of oxidized vapors.Because SOA composition appears to be governed primarily by gas-phase OH oxidation processes, our results suggest that either flow reactors or chambers are properly characterizing SOA oxidative aging mechanisms representa-Introduction

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Full tive of ambient conditions.However, SOA yields appear highly sensitive to the relative timescales of gas-phase OH oxidation and condensation processes.Simple calculations and measurements with seed particles suggest that condensation processes may be residence-time-limited in flow reactors depending on the mass accommodation coefficient of the oxidized vapors onto pre-existing particles.This could lead to underestimation of SOA yields.On the other hand, running an environmental chamber or flow reactor under conditions where partitioning is overestimated relative to atmospheric conditions will lead to a corresponding overestimation of SOA yields.Environmental chambers are commonly used to constrain SOA yields at low OH exposures, but flow reactors are needed to constrain SOA yields at higher OH exposures than 1-2 days of equivalent atmospheric oxidation, because environmental chamber SOA yield measurements appear to significantly underestimate atmospheric SOA formation rates when extrapolated over multiple days of equivalent atmospheric oxidation.Introduction

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Full Discussion Paper | Discussion Paper | Discussion Paper | Discussion Paper | Discussion Paper | Discussion Paper |

13. 3 L
glass cylindrical chamber, 46 cm long × 22 cm ID and is operated in continuous flow mode with an average residence time of 100 s.The RH in the reactor was controlled in the range of 30-40 %.The Caltech, MIT, PSI and CMU Teflon chambers range from 7.5 to 28 m 3 in volume and are operated in batch or semi-batch mode with experimental residence times ranging from 4 to 10 h.The relative humidity (RH) in the Caltech, MIT and CMU chamber experiments was less than 10 %, and the RH in the PSI chamber experiments was controlled in the range of 40-50 %.A summary of Discussion Paper | Discussion Paper | Discussion Paper |

− 3 .
The corresponding OH exposures ranged from 2.0 × 10 10 to 2.2 × 10 12 molec cm −3 s or approximately 0.2 to 17 days of equivalent atmospheric exposure.In the environmental chambers, OH radicals were generated by UV photolysis (λ = 350 nm) of hydrogen peroxide (H 2 O 2 ) with no added NO x , or by UV photolysis of nitrous acid (HONO) or methyl nitrite (CH 3 ONO) with NO x .In the present studies, OH radicals generated in the Caltech chamber were formed from photolysis of H 2 O 2 , HONO, or CH 3 ONO, depending on the experiment, whereas OH radicals generated in the MIT, PSI and CMU chambers were formed exclusively from HONO photolysis.Typical chamber OH concentrations were approximately 2 HONO) during the initial stage of chamber experiments.Corresponding OH exposures ranged from 5.4 × 10 10 to 4.0 × 10 11 molec cm −3 s (Tab.1), equivalent to approximately 0.4 to 3 days of atmospheric exposure at a typical 24 h average OH concentration of 1.5 × 10 6 molec cm −3 (Mao et al., 2009)Discussion Paper | Discussion Paper | Discussion Paper | Screen / Esc Printer-friendly Version Interactive Discussion Discussion Paper | Discussion Paper | Discussion Paper | Discussion Paper | Screen / Esc Printer-friendly Version Interactive Discussion Discussion Paper | Discussion Paper | Discussion Paper | Discussion Paper | 3 Results and discussion 3.1 Sample mass spectra of flow reactor-and chamber-generated SOA

2 =
0.93 (α-pinene SOA) and r 2 = 0.94 (naphthalene SOA) as noted in the Fig. 2 inset.For example, α-pinene SOA spectra are dominated by signals at m/z = 43 (C 2 H 3 O + ) indicative of carbonyls, and several ion clusters below m/z < 100 containing signals that are indicative of cycloalkyl fragments such as m/z = 27, 41, and 55.On the other hand, AMS spectra of naphthalene SOA are dominated by m/z = 44 (CO + 2 ), indicative of carboxylic acids, as well as signals that are indicative of aromatic compounds such as m/z = 50-51, 65, and 76-77.As is evident from Fig. 2, α-pinene and naphthalene SOA mass spectra display pronounced differences: r 2 = 0.32 between spectra shown in Fig. 2c and d.

3. 2 H
/C, O/C ratios for flow reactor-and chamber-generated SOA H/C and O/C ratios obtained from mass spectra such as shown in Fig. 3 provide information about the nature of SOA formation.Van Krevelen diagrams that show H/C ratios as a function of O/C ratios have been used to deduce oxidation reaction mech-Discussion Paper | Discussion Paper | Discussion Paper | Discussion Paper | Discussion Paper | Discussion Paper | Discussion Paper | Discussion Paper | Discussion Paper | Discussion Paper | Discussion Paper | Discussion Paper |

− 3 s
figures that adding sulfate seeds significantly increases the SOA yield.At an OH exposure of 7.8 × 10 11 molec cm −3 s and a sulfate seed particle concentrations of 20 µgm −3 , the yield of isoprene SOA increases from 0.032 to approximately 0.14 in the presence Discussion Paper | Discussion Paper | Discussion Paper |