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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Atmos. Chem. Phys.</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-14-11657-2014</article-id>
<title-group>
<article-title>A pathway analysis of global aerosol processes</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Schutgens</surname>
<given-names>N. A. J.</given-names>
<ext-link>https://orcid.org/0000-0001-9805-6384</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Stier</surname>
<given-names>P.</given-names>
<ext-link>https://orcid.org/0000-0002-1191-0128</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Department of Physics, University of Oxford, Parks Road, Oxford, OX1 3PU, UK</addr-line>
</aff>
<pub-date pub-type="epub">
<day>06</day>
<month>11</month>
<year>2014</year>
</pub-date>
<volume>14</volume>
<issue>21</issue>
<fpage>11657</fpage>
<lpage>11686</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2014 N. A. J. Schutgens</copyright-statement>
<copyright-year>2014</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 3.0 Unported License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/3.0/">https://creativecommons.org/licenses/by/3.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://acp.copernicus.org/articles/14/11657/2014/acp-14-11657-2014.html">This article is available from https://acp.copernicus.org/articles/14/11657/2014/acp-14-11657-2014.html</self-uri>
<self-uri xlink:href="https://acp.copernicus.org/articles/14/11657/2014/acp-14-11657-2014.pdf">The full text article is available as a PDF file from https://acp.copernicus.org/articles/14/11657/2014/acp-14-11657-2014.pdf</self-uri>
<abstract>
<p>We present a detailed budget of the changes in atmospheric aerosol mass and
numbers due to various processes: emission (including instant condensation of
soluble biogenic emissions), nucleation, coagulation, H&lt;sub&gt;2&lt;/sub&gt;SO&lt;sub&gt;4&lt;/sub&gt;
condensation and in-cloud production, aging and deposition. The budget is
created from monthly averaged tracer tendencies calculated by the global
aerosol model ECHAM5.5-HAM2 and allows us to investigate process
contributions at various length-scales and timescales. As a result, we show in
unprecedented detail what processes drive the evolution of aerosol. In
particular, we show that the processes that affect aerosol masses are quite
different from those that affect aerosol numbers. Condensation of H&lt;sub&gt;2&lt;/sub&gt;SO&lt;sub&gt;4&lt;/sub&gt;
gas onto pre-existing particles is an important process, dominating the
growth of small particles in the nucleation mode to the Aitken mode and the
aging of hydrophobic matter. Together with in-cloud production of
H&lt;sub&gt;2&lt;/sub&gt;SO&lt;sub&gt;4&lt;/sub&gt;, it significantly contributes to (and often dominates) the mass
burden (and hence composition) of the hydrophilic Aitken and accumulation
mode particles. Particle growth itself is the leading source of number
densities in the hydrophilic Aitken and accumulation modes, with their
hydrophobic counterparts contributing (even locally) relatively little. As
expected, the coarse mode is dominated by primary emissions and mostly
decoupled from the smaller modes. Our analysis also suggests that coagulation
serves mainly as a loss process for number densities and that, relative to
other processes, it is a rather unimportant contributor to composition
changes of aerosol. The analysis is extended with sensitivity studies where
the impact of a lower model resolution or pre-industrial emissions is shown
to be small. We discuss the use of the current budget for model
simplification, prioritization of model improvements, identification of
potential structural model errors and model evaluation against observations.</p>
</abstract>
<counts><page-count count="30"/></counts>
<funding-group>
<award-group id="gs1">
<funding-source>Natural Environment Research Council</funding-source>
<award-id>NE/G006148/1</award-id>
</award-group>
</funding-group>
</article-meta>
</front>
<body/>
<back>
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