<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "https://jats.nlm.nih.gov/nlm-dtd/publishing/3.0/journalpublishing3.dtd">
<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" article-type="research-article" dtd-version="3.0" xml:lang="en">
<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Atmos. Chem. Phys.</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-13-9801-2013</article-id>
<title-group>
<article-title>Tropical tropopause ice clouds: a dynamic approach to the mystery of low crystal numbers</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Spichtinger</surname>
<given-names>P.</given-names>
<ext-link>https://orcid.org/0000-0003-4008-4977</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Krämer</surname>
<given-names>M.</given-names>
<ext-link>https://orcid.org/0000-0002-2888-1722</ext-link>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Institut für Physik der Atmosphäre, Johannes Gutenberg-Universität, Mainz, Germany</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Institut für Energie- und Klimaforschung (IEK-7), Forschungszentrum Jülich, Jülich, Germany</addr-line>
</aff>
<pub-date pub-type="epub">
<day>07</day>
<month>10</month>
<year>2013</year>
</pub-date>
<volume>13</volume>
<issue>19</issue>
<fpage>9801</fpage>
<lpage>9818</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2013 P. Spichtinger</copyright-statement>
<copyright-year>2013</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 3.0 Unported License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/3.0/">https://creativecommons.org/licenses/by/3.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://acp.copernicus.org/articles/13/9801/2013/acp-13-9801-2013.html">This article is available from https://acp.copernicus.org/articles/13/9801/2013/acp-13-9801-2013.html</self-uri>
<self-uri xlink:href="https://acp.copernicus.org/articles/13/9801/2013/acp-13-9801-2013.pdf">The full text article is available as a PDF file from https://acp.copernicus.org/articles/13/9801/2013/acp-13-9801-2013.pdf</self-uri>
<abstract>
<p>The occurrence of high, persistent ice supersaturation inside and
  outside cold cirrus in the tropical tropopause layer (TTL) remains
  an enigma that is intensely debated as the &quot;ice supersaturation
  puzzle&quot;. However, it was recently confirmed that observed
  supersaturations are consistent with very low ice crystal
  concentrations, which is incompatible with the idea that homogeneous
  freezing is the major method of ice formation in the TTL.  Thus, the
  tropical tropopause &quot;ice supersaturation puzzle&quot; has become an &quot;ice
  nucleation puzzle&quot;.  To explain the low ice crystal concentrations,
  a number of mainly heterogeneous freezing methods have been
  proposed.  Here, we reproduce in situ measurements of frequencies of
  occurrence of ice crystal concentrations by extensive model
  simulations, driven by the special dynamic conditions in the TTL,
  namely the superposition of slow large-scale updraughts with
  high-frequency short waves.  From the simulations, it follows that
  the full range of observed ice crystal concentrations can be
  explained when the model results are composed from scenarios with
  consecutive heterogeneous and homogeneous ice formation and scenarios
  with pure homogeneous ice formation occurring in very slow (&lt; 1 cm s&lt;sup&gt;−1&lt;/sup&gt;)
  and faster (&gt; 1 cm s&lt;sup&gt;−1&lt;/sup&gt;) large-scale updraughts,
  respectively.  This statistical analysis shows that about 80% of
  TTL cirrus can be explained by &quot;classical&quot; homogeneous ice
  nucleation, while the remaining 20% stem from heterogeneous and
  homogeneous freezing occurring within the same environment. The
  mechanism limiting ice crystal production via homogeneous freezing
  in an environment full of gravity waves is the shortness of the
  gravity waves, which stalls freezing events before a higher ice
  crystal concentration can be formed.</p>
</abstract>
<counts><page-count count="18"/></counts>
</article-meta>
</front>
<body/>
<back>
<ref-list>
<title>References</title>
<ref id="ref1">
<label>1</label><mixed-citation publication-type="other" xlink:type="simple">Barahona, D. and Nenes, A. : Parameterization of cirrus cloud formation in large-scale models: Homogeneous nucleation, J. Geophys. Res., 113, D11211, &lt;a href=&quot;http://dx.doi.org/10.1029/2007JD009355&quot;&gt;https://doi.org/10.1029/2007JD009355&lt;/a&gt;, 2008.</mixed-citation>
</ref>
<ref id="ref2">
<label>2</label><mixed-citation publication-type="other" xlink:type="simple">Barahona, D. and Nenes, A.: Dynamical states of low temperature cirrus. Atmos. Chem. Phys., 11, 3757–3771, &lt;a href=&quot;http://dx.doi.org/10.5194/acp-11-3757-2011&quot;&gt;https://doi.org/10.5194/acp-11-3757-2011&lt;/a&gt;, 2011.</mixed-citation>
</ref>
<ref id="ref3">
<label>3</label><mixed-citation publication-type="other" xlink:type="simple">Boehm, M. D. and Verlinde, J.: Stratospheric influence on upper tropospheric tropical cirrus, Geophys. Res. Lett., 27, 3209–3212, 2000.</mixed-citation>
</ref>
<ref id="ref4">
<label>4</label><mixed-citation publication-type="other" xlink:type="simple">Bretherton, C. S. and Smolarkiewicz, P. K.: Gravity waves, compensating subsidence and detrainment around cumulus clouds, J. Atmos. Sci., 46, 740–759, 1989.</mixed-citation>
</ref>
<ref id="ref5">
<label>5</label><mixed-citation publication-type="other" xlink:type="simple">DeMott, P., Cziczo, D., Prenni, A., Murphy, D., Kreidenweis, S., Thomson, D., Borys, R., and Rogers, D.: Measurements of the concentration and composition of nuclei for cirrus formation, P. Natl. Acad. Sci., 100, 14655–14660, 2003.</mixed-citation>
</ref>
<ref id="ref6">
<label>6</label><mixed-citation publication-type="other" xlink:type="simple">Flury, T., Wu, D. L., and Read, W. G.: Correlation among cirrus ice content, water vapor and temperature in the TTL as observed by CALIPSO and Aura/MLS, Atmos. Chem. Phys., 12, 683–691, &lt;a href=&quot;http://dx.doi.org/10.5194/acp-12-683-2012&quot;&gt;https://doi.org/10.5194/acp-12-683-2012&lt;/a&gt;, 2012.</mixed-citation>
</ref>
<ref id="ref7">
<label>7</label><mixed-citation publication-type="other" xlink:type="simple">Forster, P. M. and Shine, K. P.: Assessing the climate impact of trends in stratospheric water vapor, Geophys. Res. Lett., 29, 1086, &lt;a href=&quot;http://dx.doi.org/10.1029/2001GL013909&quot;&gt;https://doi.org/10.1029/2001GL013909&lt;/a&gt;, 2002.</mixed-citation>
</ref>
<ref id="ref8">
<label>8</label><mixed-citation publication-type="other" xlink:type="simple">Fueglistaler, S., Dessler, A. E., Dunkerton, T. J., Folkins, I., Fu, Q., and Mote, P. W.: Tropical Tropopause Layer, Rev. Geophys., 47, RG1004, &lt;a href=&quot;http://dx.doi.org/10.1029/2008RG000267&quot;&gt;https://doi.org/10.1029/2008RG000267&lt;/a&gt;, 2009a.</mixed-citation>
</ref>
<ref id="ref9">
<label>9</label><mixed-citation publication-type="other" xlink:type="simple">Fueglistaler, S., Legras, B., Beljaars, A., Morcrette, J.-J., Simmons, A., Tompkins, A. M., and Uppala, S.: The diabatic heat budget of the upper troposphere and lower/mid stratosphere in ECMWF reanalyses, Q. J. Roy. Meteor. Soc., 135, 21–37, 2009b.</mixed-citation>
</ref>
<ref id="ref10">
<label>10</label><mixed-citation publication-type="other" xlink:type="simple">Froyd, K. D., Murphy, D. M., Sanford, T. J., Thomson, D. S., Wilson, J. C., Pfister, L., and Lait, L.: Aerosol composition of the tropical upper troposphere, Atmos. Chem. Phys., 9, 4363–4385, &lt;a href=&quot;http://dx.doi.org/10.5194/acp-9-4363-2009&quot;&gt;https://doi.org/10.5194/acp-9-4363-2009&lt;/a&gt;, 2009.</mixed-citation>
</ref>
<ref id="ref11">
<label>11</label><mixed-citation publication-type="other" xlink:type="simple">Fritts, D. C. and Alexander, M. J.: Gravity wave dynamics and effects in the middle atmosphere, Rev. Geophys., 41, 1003, &lt;a href=&quot;http://dx.doi.org/10.1029/2001RG000106&quot;&gt;https://doi.org/10.1029/2001RG000106&lt;/a&gt;, 2003.</mixed-citation>
</ref>
<ref id="ref12">
<label>12</label><mixed-citation publication-type="other" xlink:type="simple">Fujiwara, M., Iwasaki, S., Shimizu, A., Inai, Y., Shiotani, M., Hasebe, F., Matsui, I., Sugimoto, N., Okamoto, H., Nishi, N., Hamada, A., Sakazaki, T., and Yoneyama, K.: Cirrus observations in the tropical tropopause layer over the western Pacific, J. Geophys. Res., 114, D09304, &lt;a href=&quot;http://dx.doi.org/10.1029/2008JD011040&quot;&gt;https://doi.org/10.1029/2008JD011040&lt;/a&gt;, 2009.</mixed-citation>
</ref>
<ref id="ref13">
<label>13</label><mixed-citation publication-type="other" xlink:type="simple">Gary, B. L.: Mesoscale temperature fluctuations in the stratosphere, Atmos. Chem. Phys., 6, 4577–4589, &lt;a href=&quot;http://dx.doi.org/10.5194/acp-6-4577-2006&quot;&gt;https://doi.org/10.5194/acp-6-4577-2006&lt;/a&gt;, 2006.</mixed-citation>
</ref>
<ref id="ref14">
<label>14</label><mixed-citation publication-type="other" xlink:type="simple">Gensch, I., Bunz, H., Baumgardner, D., Christensen, L., Fahey, D., Hermann, R., Lawson, P., Popp, P., Smith, J., Webster, C., Weinstock, E., Wilson, J., Peter, T., and Krämer, M.: Supersaturations, Microphysics and Nitric Acid Partitioning in a Cold Cirrus observed during CR-AVE 2006: An Observation-Modeling Intercomparison Study, Environ. Res. Lett., 3, 035003, &lt;a href=&quot;http://dx.doi.org/10.1088/1748-9326/3/3/035003&quot;&gt;https://doi.org/10.1088/1748-9326/3/3/035003&lt;/a&gt;, 2008.</mixed-citation>
</ref>
<ref id="ref15">
<label>15</label><mixed-citation publication-type="other" xlink:type="simple">Gierens, K., Kohlhepp, R., Dotzek, N., and Smit, H. G.: Instantaneous fluctuations of temperature and moisture in the upper troposphere and tropopause region. Part 1: Probability densities and their variability, Meteorol. Z., 16, 221–231, 2007.</mixed-citation>
</ref>
<ref id="ref16">
<label>16</label><mixed-citation publication-type="other" xlink:type="simple">Gill, A. E.: Some simple solutions for heat-induced tropical circulation, Q. J. Roy. Meteor. Soc., 106, 447–462, 1980.</mixed-citation>
</ref>
<ref id="ref17">
<label>17</label><mixed-citation publication-type="other" xlink:type="simple">Hertzog, A. and Vial, F.: A study of the dynamics of the equatorial lower stratosphere by use of ultra-long-duration balloons 2. Gravity waves, J. Geophys. Res., 106, 22745–22761, 2001.</mixed-citation>
</ref>
<ref id="ref18">
<label>18</label><mixed-citation publication-type="other" xlink:type="simple">Hoyle, C., Luo, B., and Peter, T.: The Origin of High Ice Crystal Number Densities in Cirrus Clouds, J. Atmos. Sci., 62, 2568–2579, 2005.</mixed-citation>
</ref>
<ref id="ref19">
<label>19</label><mixed-citation publication-type="other" xlink:type="simple">Immler, F., Krüger, K., Fujiwara, M., Verver, G., Rex, M., and Schrems, O.: Correlation between equatorial Kelvin waves and the occurrence of extremely thin ice clouds at the tropical tropopause, Atmos. Chem. Phys., 8, 4019–4026, &lt;a href=&quot;http://dx.doi.org/10.5194/acp-8-4019-2008&quot;&gt;https://doi.org/10.5194/acp-8-4019-2008&lt;/a&gt;, 2008.</mixed-citation>
</ref>
<ref id="ref20">
<label>20</label><mixed-citation publication-type="other" xlink:type="simple">Jensen, E. and Pfister, L.: Transport and freeze-drying in the tropical tropopause layer, J. Geophys. Res., 109, D02207, &lt;a href=&quot;http://dx.doi.org/10.1029/2003JD004022&quot;&gt;https://doi.org/10.1029/2003JD004022&lt;/a&gt;, 2004.</mixed-citation>
</ref>
<ref id="ref21">
<label>21</label><mixed-citation publication-type="other" xlink:type="simple">Jensen, E. J., Pfister, L., Bui, T. V., Lawson, P., Baker, B., Mo, Q., Baumgardner, D., Weinstock, E. M., Smith, J. B., Moyer, E. J., Hanisco, T. F., Sayres, D. S., Clair, J. M. St., Alexander, M. J., Toon, O. B., and Smith, J. A.: Formation of large ($\backsimeq$ 100 &lt;abbr&gt;μm&lt;/abbr&gt;) ice crystals near the tropical tropopause, Atmos. Chem. Phys., 8, 1621–1633, &lt;a href=&quot;http://dx.doi.org/10.5194/acp-8-1621-2008&quot;&gt;https://doi.org/10.5194/acp-8-1621-2008&lt;/a&gt;, 2008.</mixed-citation>
</ref>
<ref id="ref22">
<label>22</label><mixed-citation publication-type="other" xlink:type="simple">Jensen, E. J., Pfister, L., Bui, T.-P., Lawson, P., and Baumgardner, D.: Ice nucleation and cloud microphysical properties in tropical tropopause layer cirrus, Atmos. Chem. Phys., 10, 1369–1384, &lt;a href=&quot;http://dx.doi.org/10.5194/acp-10-1369-2010&quot;&gt;https://doi.org/10.5194/acp-10-1369-2010&lt;/a&gt;, 2010.</mixed-citation>
</ref>
<ref id="ref23">
<label>23</label><mixed-citation publication-type="other" xlink:type="simple">Jensen, E. J., Diskin, G., Lawson, R. P., Lance, S., Bui, T. P., Hlavka, D., McGill, M., Pfister, L., Toon, O. B., and Gao, R.: Ice nucleation and dehydration in the Tropical Tropopause Layer, P. Natl. Acad. Sci., 110, 2041–2046, &lt;a href=&quot;http://dx.doi.org/10.1073/pnas.1217104110&quot;&gt;https://doi.org/10.1073/pnas.1217104110&lt;/a&gt;, 2013.</mixed-citation>
</ref>
<ref id="ref24">
<label>24</label><mixed-citation publication-type="other" xlink:type="simple">Kajikawa, M. and Heymsfield, A.: Aggregation of ice crystals, J. Atmos. Sci., 46, 3108–3121, 1989.</mixed-citation>
</ref>
<ref id="ref25">
<label>25</label><mixed-citation publication-type="other" xlink:type="simple">Kärcher, B. and Koop, T.: The role of organic aerosols in homogeneous ice formation, Atmos. Chem. Phys., 5, 703–714, &lt;a href=&quot;http://dx.doi.org/10.5194/acp-5-703-2005&quot;&gt;https://doi.org/10.5194/acp-5-703-2005&lt;/a&gt;, 2005.</mixed-citation>
</ref>
<ref id="ref26">
<label>26</label><mixed-citation publication-type="other" xlink:type="simple">Kärcher, B. and Lohmann, U.: A parameterization of cirrus cloud formation: Homogeneous freezing of supercooled aerosols, J. Geophys. Res., 107, 4010, &lt;a href=&quot;http://dx.doi.org/10.1029/2001JD000470&quot;&gt;https://doi.org/10.1029/2001JD000470&lt;/a&gt;, 2002.</mixed-citation>
</ref>
<ref id="ref27">
<label>27</label><mixed-citation publication-type="other" xlink:type="simple">Khvorostyanov, V., Morrison, H., Curry, J., Baumgardner, D., and Lawson, P.: High supersaturation and modes of ice nucleation in thin tropopause cirrus: Simulation of the 13 July 2002 Cirrus Regional Study of Tropical Anvils and Cirrus Layers case, J. Geophys. Res., 111, D02201, &lt;a href=&quot;http://dx.doi.org/10.1029/2004JD005235&quot;&gt;https://doi.org/10.1029/2004JD005235&lt;/a&gt;, 2006.</mixed-citation>
</ref>
<ref id="ref28">
<label>28</label><mixed-citation publication-type="other" xlink:type="simple">Koop, T., Luo, B., Tsias, A., and Peter, T.: Water activity as the determinant for homogeneous ice nucleation in aqueous solutions, Nature, 406, 611–614, 2000.</mixed-citation>
</ref>
<ref id="ref29">
<label>29</label><mixed-citation publication-type="other" xlink:type="simple">Korolev, A. and Mazin, I.: Supersaturation of Water Vapor in Clouds, J. Atmos. Sci., 60, 2957–2974, 2003.</mixed-citation>
</ref>
<ref id="ref30">
<label>30</label><mixed-citation publication-type="other" xlink:type="simple">Krämer, M., Schiller, C., Afchine, A., Bauer, R., Gensch, I., Mangold, A., Schlicht, S., Spelten, N., Sitnikov, N., Borrmann, S., de Reus, M., and Spichtinger, P.: Ice supersaturations and cirrus cloud crystal numbers, Atmos. Chem. Phys., 9, 3505–3522, &lt;a href=&quot;http://dx.doi.org/10.5194/acp-9-3505-2009&quot;&gt;https://doi.org/10.5194/acp-9-3505-2009&lt;/a&gt;, 2009.</mixed-citation>
</ref>
<ref id="ref31">
<label>31</label><mixed-citation publication-type="other" xlink:type="simple">Lawson, R. P., Pilson, B., Baker, B., Mo, Q., Jensen, E., Pfister, L., and Bui, P.: Aircraft measurements of microphysical properties of subvisible cirrus in the tropical tropopause layer, Atmos. Chem. Phys., 8, 1609–1620, &lt;a href=&quot;http://dx.doi.org/10.5194/acp-8-1609-2008&quot;&gt;https://doi.org/10.5194/acp-8-1609-2008&lt;/a&gt;, 2008.</mixed-citation>
</ref>
<ref id="ref32">
<label>32</label><mixed-citation publication-type="other" xlink:type="simple">Lin, H., Noone, K. J., Ström, J., and Heymsfield, A. J.: Dynamical Influences on Cirrus Cloud Formation Process, J. Atmos. Sci., 55, 1940–1949, 1998.</mixed-citation>
</ref>
<ref id="ref33">
<label>33</label><mixed-citation publication-type="other" xlink:type="simple">McFarquhar, G. M., Heymsfield, A. J., Spinhirne, J., and Hart, B.: Thin and Subvisual Tropopause Tropical Cirrus: Observations and Radiative Impacts, J. Atmos. Sci., 57, 1841–1853, 2000.</mixed-citation>
</ref>
<ref id="ref34">
<label>34</label><mixed-citation publication-type="other" xlink:type="simple">Murray, B. J.: Inhibition of ice crystallisation in highly viscous aqueous organic acid droplets, Atmos. Chem. Phys., 8, 5423–5433, &lt;a href=&quot;http://dx.doi.org/10.5194/acp-8-5423-2008&quot;&gt;https://doi.org/10.5194/acp-8-5423-2008&lt;/a&gt;, 2008.</mixed-citation>
</ref>
<ref id="ref35">
<label>35</label><mixed-citation publication-type="other" xlink:type="simple">Murray, B., Wilson, T. W., Dobbie, S., Cui, Z., Al-Jumur, S. M. R. K., Möhler, O., Schnaiter, M., Wagner, R., Benz, S., Niemand, M., Saathoff, H., Ebert, V., Wagner, S., and Kärcher, B.: Heterogeneous nucleation of ice particles on glassy aerosols under cirrus conditions, Nat. Geosci., 3, 233–237, &lt;a href=&quot;http://dx.doi.org/10.1038/NGEO817&quot;&gt;https://doi.org/10.1038/NGEO817&lt;/a&gt;, 2010.</mixed-citation>
</ref>
<ref id="ref36">
<label>36</label><mixed-citation publication-type="other" xlink:type="simple">Peter, T., Marcolli, C., Spichtinger, P., Corti, T., Baker, M. B., and Koop, T.: When dry air is too humid, Science, 314, 1399–1402, 2006.</mixed-citation>
</ref>
<ref id="ref37">
<label>37</label><mixed-citation publication-type="other" xlink:type="simple">Ruprecht, D. and Klein, R.: A Model for Nonlinear Interactions of Internal Gravity Waves with Saturated Regions, Meteorol. Z., 20, 243–252, 2011.</mixed-citation>
</ref>
<ref id="ref38">
<label>38</label><mixed-citation publication-type="other" xlink:type="simple">Ruprecht, D., Klein, R., and Majda, A. J.: Modulation of Internal Gravity Waves in a Multiscale Model for Deep Convection on Mesoscales, J. Atmos. Sci., 67, 2504–2519, 2010.</mixed-citation>
</ref>
<ref id="ref39">
<label>39</label><mixed-citation publication-type="other" xlink:type="simple">Ryu, J.-H. and Lee, S.: Effect of Tropical Waves on the Tropical Tropopause Transition Layer Upwelling, J. Atmos. Sci., 67, 3130–3148, 2010.</mixed-citation>
</ref>
<ref id="ref40">
<label>40</label><mixed-citation publication-type="other" xlink:type="simple">Salby, M. and Callaghan, P.: Control of the Tropical Tropopause and Vertical Transport across It, J. Climate, 17, 965–985, 2004.</mixed-citation>
</ref>
<ref id="ref41">
<label>41</label><mixed-citation publication-type="other" xlink:type="simple">Schiller, C., Krämer, M., Afchine, A., Spelten, N., and Sitnikov, N.: The ice Water Content in Arctic, Midlatitude and Tropical Cirrus, J. Geophys. Res., 113, D24208, &lt;a href=&quot;http://dx.doi.org/10.1029/2008JD010342&quot;&gt;https://doi.org/10.1029/2008JD010342&lt;/a&gt;, 2008.</mixed-citation>
</ref>
<ref id="ref42">
<label>42</label><mixed-citation publication-type="other" xlink:type="simple">Seifert, A. and Beheng, K. D.: : A two-moment cloud microphysics parameterization for mixed-phase clouds. Part 1: Model description, Meteorol. Atmos. Phys., 92, 45–66, 2006.</mixed-citation>
</ref>
<ref id="ref43">
<label>43</label><mixed-citation publication-type="other" xlink:type="simple">Selkirk, H. B., Vömel, H., Valverde Canossa, J. M., Pfister, L., Diaz, J. A., Fernández, W., Amador, J., Stolz, W., and Peng, G. S.: Detailed structure of the tropical upper troposphere and lower stratosphere as revealed by balloon sonde observations of water vapor, ozone, temperature, and winds during the NASA TCSP and TC4 campaigns, J. Geophys. Res., 115, D00J19, &lt;a href=&quot;http://dx.doi.org/10.1029/2009JD013209&quot;&gt;https://doi.org/10.1029/2009JD013209&lt;/a&gt;, 2010.</mixed-citation>
</ref>
<ref id="ref44">
<label>44</label><mixed-citation publication-type="other" xlink:type="simple">Spichtinger, P. and Cziczo, D. J.: Impact of heterogeneous ice nuclei on homogeneous freezing events in cirrus clouds, J. Geophys. Res., 15, D14208, &lt;a href=&quot;http://dx.doi.org/10.1029/2009JD012168&quot;&gt;https://doi.org/10.1029/2009JD012168&lt;/a&gt;, 2010.</mixed-citation>
</ref>
<ref id="ref45">
<label>45</label><mixed-citation publication-type="other" xlink:type="simple">Spichtinger, P. and Gierens, K. M.: Modelling of cirrus clouds – Part 1a: Model description and validation, Atmos. Chem. Phys., 9, 685–706, &lt;a href=&quot;http://dx.doi.org/10.5194/acp-9-685-2009&quot;&gt;https://doi.org/10.5194/acp-9-685-2009&lt;/a&gt;, 2009a.</mixed-citation>
</ref>
<ref id="ref46">
<label>46</label><mixed-citation publication-type="other" xlink:type="simple">Spichtinger, P. and Gierens, K. M.: Modelling of cirrus clouds – Part 1b: Structuring cirrus clouds by dynamics, Atmos. Chem. Phys., 9, 707–719, &lt;a href=&quot;http://dx.doi.org/10.5194/acp-9-707-2009&quot;&gt;https://doi.org/10.5194/acp-9-707-2009&lt;/a&gt;, 2009b.</mixed-citation>
</ref>
<ref id="ref47">
<label>47</label><mixed-citation publication-type="other" xlink:type="simple">Spichtinger, P. and Gierens, K. M.: Modelling of cirrus clouds – Part 2: Competition of different nucleation mechanisms, Atmos. Chem. Phys., 9, 2319–2334, &lt;a href=&quot;http://dx.doi.org/10.5194/acp-9-2319-2009&quot;&gt;https://doi.org/10.5194/acp-9-2319-2009&lt;/a&gt;, 2009c.</mixed-citation>
</ref>
<ref id="ref48">
<label>48</label><mixed-citation publication-type="other" xlink:type="simple">Thomas, A., Borrmann, S., Kiemle, C., Cairo, F., Volk, M., Beuermann, J., Lepuchov, B., Santacesaria, V., Matthey, R., Rudakov, V., Yushkov, V., MacKenzie, A. R., and Stefanutti, L.: In situ measurements of background aerosol and subvisible cirrus in the tropical tropopause region, J. Geophys. Res., 107, 4763, &lt;a href=&quot;http://dx.doi.org/10.1029/2001JD001385&quot;&gt;https://doi.org/10.1029/2001JD001385&lt;/a&gt;, 2002.</mixed-citation>
</ref>
<ref id="ref49">
<label>49</label><mixed-citation publication-type="other" xlink:type="simple">Thompson, A. M., Witte, J. C., McPeters, R. D., Oltmans, S. J., Schmidlin, F. J., Logan, J. A., Fujiwara, M., Kirchhoff, V. W. J. H., Posny, F., Coetzee, G. J. R., Hoegger, B., Kawakami, S., Ogawa, T., Johnson, B. J., Vömel, H., and Labow, G.: Southern Hemisphere Additional Ozonesondes (SHADOZ) 1998–2000 tropical ozone climatology 1. Comparison with Total Ozone Mapping Spectrometer (TOMS) and ground-based measurements, J. Geophys. Res., 108, 8238, &lt;a href=&quot;http://dx.doi.org/10.1029/2001JD000967&quot;&gt;https://doi.org/10.1029/2001JD000967&lt;/a&gt;, 2003.</mixed-citation>
</ref>
<ref id="ref50">
<label>50</label><mixed-citation publication-type="other" xlink:type="simple">Thompson, A. M., Allen, A. L., Lee, S., Miller, S. K., and Witte, J. C.: Gravity and Rossby wave signatures in the tropical troposphere and lower stratosphere based on Southern Hemisphere Additional Ozonesondes (SHADOZ), 1998–2007, J. Geophys. Res., 116, D05302, &lt;a href=&quot;http://dx.doi.org/10.1029/2009JD013429&quot;&gt;https://doi.org/10.1029/2009JD013429&lt;/a&gt;, 2011.</mixed-citation>
</ref>
<ref id="ref51">
<label>51</label><mixed-citation publication-type="other" xlink:type="simple">Vial, F., Hertzog, A., Mechoso, C. R., Basdevant, C., Cocquerez, P., Dubourg, V., and Nouel, F.: A study of the dynamics of the equatorial lower stratosphere by use of ultra-long-duration balloons, 1. Planetary scales, J. Geophys. Res., 106, 22725–22743, 2001.</mixed-citation>
</ref>
<ref id="ref52">
<label>52</label><mixed-citation publication-type="other" xlink:type="simple">Virts, K.: Cirrus in the Tropical Tropopause Transition Layer: Formation Mechanisms and Influence of the Local and Planetary-Scale Environment, MSc thesis, University of Washington, 108 pp., available at: &lt;a href=&quot;http://www.atmos.washington.edu/ kvirts/docs/Thesis.pdf&quot;&gt;http://www.atmos.washington.edu/ kvirts/docs/Thesis.pdf&lt;/a&gt;, 2009</mixed-citation>
</ref>
<ref id="ref53">
<label>53</label><mixed-citation publication-type="other" xlink:type="simple">Virts, K., Wallace, J., Fu, Q., and Ackermann, T.: Tropical Tropopause Transition Layer Cirrus as Represented by CALIPSO Lidar Observations, J. Atmos. Sci., 67, 3113–3129, 2010.</mixed-citation>
</ref>
<ref id="ref54">
<label>54</label><mixed-citation publication-type="other" xlink:type="simple">Wang, L., Alexander, M. J., Bui, T. B., and Mahoney, M. J.: Small-scale gravity waves in ER-2 MMS/MTP wind and temperature measurements during CRYSTAL-FACE, Atmos. Chem. Phys., 6, 1091–1104, &lt;a href=&quot;http://dx.doi.org/10.5194/acp-6-1091-2006&quot;&gt;https://doi.org/10.5194/acp-6-1091-2006&lt;/a&gt;, 2006.</mixed-citation>
</ref>
<ref id="ref55">
<label>55</label><mixed-citation publication-type="other" xlink:type="simple">Webster, P. J.: Response of the tropical atmosphere to local, steady forcing, Mon. Weather Rev., 100, 518–541, 1972.</mixed-citation>
</ref>
<ref id="ref56">
<label>56</label><mixed-citation publication-type="other" xlink:type="simple">Weisenstein, D. K., Penner, J. E., Herzog, M., and Liu, X.: Global 2-D intercomparison of sectional and modal aerosol modules, Atmos. Chem. Phys., 7, 2339–2355, &lt;a href=&quot;http://dx.doi.org/10.5194/acp-7-2339-2007&quot;&gt;https://doi.org/10.5194/acp-7-2339-2007&lt;/a&gt;, 2007.</mixed-citation>
</ref>
<ref id="ref57">
<label>57</label><mixed-citation publication-type="other" xlink:type="simple">Wheeler, M., Kiladis, G. N., and Webster, P. J.: Large-scale dynamical fields associated with convectively coupled equatorial waves, J. Atmos. Sci., 57, 613–640, 2000.</mixed-citation>
</ref>
<ref id="ref58">
<label>58</label><mixed-citation publication-type="other" xlink:type="simple">Zobrist, B., Marcolli, C., Pedernera, D. A., and Koop, T.: Do atmospheric aerosols form glasses?, Atmos. Chem. Phys., 8, 5221–5244, &lt;a href=&quot;http://dx.doi.org/10.5194/acp-8-5221-2008&quot;&gt;https://doi.org/10.5194/acp-8-5221-2008&lt;/a&gt;, 2008.</mixed-citation>
</ref>
</ref-list>
</back>
</article>