References

ACP

Atmospheric Chemistry and Physics

ACP

Atmos. Chem. Phys.

1680-7324

Copernicus Publications

Göttingen, Germany

10.5194/acp-10-9943-2010

Interannual variability in soil nitric oxide emissions over the United States as viewed from space

Hudman

R. C.

¹ Russell

A. R.

¹ Valin

L. C.

¹ Cohen

R. C.

Department of Chemistry, University of California Berkeley, Berkeley, CA, USA

20 10 2010

10 20 9943 9952

2010

This work is licensed under the Creative Commons Attribution 3.0 Unported License. To view a copy of this licence, visit https://creativecommons.org/licenses/by/3.0/

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We examine the interannual variability in the NO2 column over North America measured by the Ozone Monitoring Instrument (OMI) in 2005–2008. By comparison to a model of soil NOx emissions driven by the North American Regional Reanalysis precipitation and 0–10 cm soil temperature fields, we show the source of this observed interannual variability over much of the central United States in June is fertilizer application. We find that dry, warm conditions followed by convective precipitation induces pulsed emissions of NOx over the agricultural Great Plains. In June 2006 we infer a 50% increase in soil NOx emission and a 30% increase in the tropospheric NO2 column relative to the June 2005–2008 mean. In a case-study of fertilized corn and soybean fields over SE South Dakota, we find an associated rain-induced pulsing event reaching 4.6×1015 molec cm−2, equivalent to a surface concentration of ~2 ppbv. We calculate that soil NOx emissions resulted in a mean daily maximum 8-h ozone enhancement over the agricultural Great Plains of 5 ppbv in June 2006 (with predicted events reaching 16 ppbv) compared with a mean enhancement of 3 ppbv for soil NOx in the years 2005–2008.

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